Spectroscopy : Volume Three /

It is fifteen years since Walker and Straw wrote the first edition of 'Spectroscopy' and considerable developments have taken place during that time in all fields of this expanding subject. In atomic spectroscopy, for example, where the principles required in a student text have been laid...

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Bibliographic Details
Main Author: Straughan, B. P
Other Authors: Walker, S
Format: Book
Language:English
Published: Dordrecht : Springer Netherlands, 1976
Subjects:
Table of Contents:
  • 1 Molecular Quantum Numbers of Diatomic Molecules
  • 1.1 Formation of molecular quantum numbers
  • 1.2 'Scripts' giving information on the wavefunction symmetry of diatomic molecules
  • 1.3 Correlation between atomic and molecular states
  • 1.4 Coupling of angular momenta
  • 1.5 Selection roles of diatomic molecules
  • 1.6 A doubling
  • 1.7 c and d classification of rotational levels
  • References
  • 2 Electronic Spectra of Gaseous Diatomic Molecules
  • 2.l Introduction
  • 2.2 Instrumentation
  • 2.3 Electronic excitation of diatomic species
  • 2.4 Electronic spectra of diatomic species in flames
  • 2.5 More recent studies of electronic spectra
  • References
  • 3 Dissociation Energies of Diatomic Molecules
  • 3.l Introduction
  • 3.2 Evaluation of D by band convergence method
  • 3.3 Evaluation of De by extrapolation to convergence limits
  • 3.4 Evaluation of D by atomic fluorescence method
  • 3.5 Predissociation and its use in evaluating D
  • 3.6 Conclusions on the determination of dissociation energies of diatomic molecules
  • 3.7 Recent dissociation energy studies for diatomic molecules
  • References
  • 4 Electronic Spectra of Polyatomic Molecules
  • 4.1 Introduction
  • 4.2 Absorption of light by a medium
  • 4.3 Instrumentation
  • 4.4 The electronic states of polyatomic molecules
  • 4.5 Interpretation of the absorption spectra of organic compounds
  • 4.6 Selection rules for electronic transitions
  • 4.7 Electronic spectra of transition metal complexes
  • 4.8 Charge transfer spectra
  • 4.9 Electronic spectra of short lived species
  • 4.10 Some applications to kinetics
  • 4.11 Optical rotatory dispersion and circular dichroism
  • References
  • 5 Fluorescence and Phosphorescence Spectroscopy
  • 5.1 Introduction
  • 5.2 Fluorescence
  • 5.3 Phosphorescence
  • 5.4 Excitation spectra
  • 5.5 Experimental methods
  • 5.6 Applications of fluroescence and phosphorescence
  • References
  • 6 Astrochemistry
  • 6.1 Introduction and instrumentation
  • 6.2 The Doppler effect
  • 6.3 Planetary atmospheres
  • 6.4 Spectra of nebulae and forbidden transitions
  • 6.5 Spectra of comets
  • 6.6 Stellar spectra
  • 6.7 Spectral studies of the interstellar medium
  • 6.8 Pulsars and quasars
  • 6.9 Space probes in the mid-seventies
  • References
  • 7 Photoelectron Spectroscopy
  • 7.1 Introduction
  • 7.2 Instrumentation
  • 7.3 Chemical information from photoelectron spectroscopy
  • 7.4 Solid state surface studies
  • 7.5 Surface charging and the calibration problem
  • 7.6 Photoelectron intensities
  • 7.7 Valence energy level studies
  • 7.8 Additional structure in U.V. photoelectron spectra
  • 7.9 Core energy level studies
  • 7.10 Additional structure in X-ray photoelectron spectra
  • References
  • A APPENDIX
  • A.1 Absorption and emission of radiation
  • A.2 Energy levels of a linear rigid motor
  • A.3 Selection rules for the linear rigid motor
  • A.4 Energy levels of a harmonic oscillator
  • A.5 Calculation of the vibrational eigen functions for a diatomic molecule
  • A.6 Selection rules for changes in vibration quantum numbers
  • A.7 Absolute intensities of absorptions
  • A.8 Electronic transition probability and spectral intensity