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|a (OCoLC)1337072223
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|a CtY
|b eng
|e rda
|e pn
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|a Charboneau, David J.,
|e author
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|a Homogeneous Organic Electron Donors in Transition Metal-Catalyzed Reductive Coupling Reactions /
|c David J Charboneau
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|a [New Haven, Connecticut] :
|b Yale University,
|c 2021
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|a 1 online resource (363 pages)
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
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|a Dissertations, Academic
|2 lcsh
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|a Advisors: Hazari, Nilay Committee members: Holland, Patrick; Mayer, James
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|a This Yale-originated record is shareable under Creative Commons license CC0
|5 CTY
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|b Ph.D
|c Yale University
|d 2021.
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|3 EliScholar dissertation:
|a Access is available to the Yale community
|5 CtY
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|3 Proquest dissertation:
|a Access is restricted by licensing agreement
|5 CtY
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|a This item is not available for online access until February 1, 2023
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|a This thesis summarizes work towards understanding the mechanism of and improving upon nickel-catalyzed reductive coupling reactions through the use of homogeneous organic reductants and understanding of the fundamental reactivity of nickel intermediates. Chapter 1 presents an overview of the utility of homogeneous organic electron donors in nickel-catalyzed reductive coupling reactions. Chapter 2 provides a mechanistic investigation into the nickel-catalyzed carboxylation of aryl halides with carbon dioxide using a homogeneous organic electron donor. In Chapter 3, a general strategy for the cross-electrophile coupling of aryl and alkyl halides is explored. In Chapter 4, the reactivity of a nickel hydride complex supported by a pincer scaffold is explored with small molecules such as N2 and CO
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|a Description based on Dissertations Abstracts International, Volume: 83-08, Section: B
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|a This item is not available for online access until February 1, 2023. Digital access copies must be provided for use. Contact the Beinecke Rare Book and Manuscript Library at beinecke.library@yale.edu to request access
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|a Chemistry
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| 650 |
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|a Organic chemistry
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| 650 |
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|a Physical chemistry
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|a Organic electron donor
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|a Reductive coupling reaction
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|a Transition metal
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| 655 |
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|a Academic theses
|2 lcgft
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| 700 |
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|a Hazari, Nilay,
|e degree supervisor
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|a Yale University
|b Department of Chemistry,
|e degree granting institution.
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| 730 |
0 |
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|3 Proquest dissertation
|a Dissertations & Theses @ Yale University
|5 CtY
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| 773 |
0 |
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|t Dissertations Abstracts International
|g 83-08B
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| 830 |
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0 |
|3 EliScholar dissertation
|a Yale Graduate School of Arts and Sciences Dissertations
|5 CtY
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1 |
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